Showing posts with label DOE. Show all posts
Showing posts with label DOE. Show all posts

Wednesday, February 18, 2009

Low Cost Solar Cells From Unconventional Material Is The Key To Solar Future

the Energy and Resources Group and the Department of Chemistry at the University of California, Berkeley, and the Lawrence Berkeley National Laboratory (LBNL) released in a form of study.

The study states that these materials are abundant and could expand the use of solar cells as a significant source of low-carbon energy.

Following is an abstract of information released by University of Berkeley (A link to the article at the end of this post);

The work provides a roadmap for research into novel solar cell types precisely when the U. S. Department of Energy and other funders plan to expand their efforts to link new basic research to deployment efforts as part of a national effort to greatly expand the use of clean energy, according to Daniel Kammen, UC Berkeley professor of energy and resources and director of the Renewable and Appropriate Energy Laboratory.

“The reason we started looking at new materials is because people often assume solar will be the dominant energy source of the future,” said Wadia, a post-doctoral researcher who spearheaded the research. “Because the sun is the Earth’s most reliable and plentiful resource, solar definitely has that potential, but current solar technology may not get us there in a timeframe that is meaningful, if at all. It’s important to be optimistic, but when considering the practicalities of a solar-dominated energy system, we must turn our attention back to basic science research if we are to solve the problem.”

The most popular solar materials in use today are silicon and thin films made of CdTe (cadmium telluride) and CIGS (copper indium gallium selenide). While these materials have helped elevate solar to a major player in renewable energy markets, they are still limited by manufacturing challenges. Silicon is expensive to process and mass produce. Furthermore, it has become increasingly difficult to mine enough silicon to meet ever-growing consumer demand.

Thin films, while significantly less costly than silicon and easier to mass produce, would rapidly deplete our natural resources if these technologies were to scale to terawatt hours of annual manufacturing production. A terawatt hour is a billion kilowatt hours.

“We believe in a portfolio of technologies and therefore continue to support the commercial development of all photovoltaic technologies,” Kammen said. “Yet, what we’ve found is that some leading thin films may be difficult to scale as high as global electricity consumption.”
“It's not to say that these materials won't play a significant role,” Wadia added, “but rather, if our objective is to supply the majority of electricity in this way, we must quickly consider alternative materials that are Earth-abundant, non-toxic and cheap. These are the materials that can get us to our goals more rapidly.”

Finding an affordable electricity supply is essential for meeting basic human needs, Kammen said, yet 30 percent of the world’s population remains without reliable or sufficient electrical energy. Scientific forecasts predict that to meet the world’s energy demands by 2050, global carbon emissions would have to grow to levels of irreversible consequences.

"As the U.S. envisions a clean energy future consistent with the vision outlined by President Obama, it is exciting that the range of promising solar cell materials is expanding, ideally just as a national renewable energy strategy takes shape," said Kammen, who is co-director of the Berkeley Institute of the Environment and UC Berkeley's Class of 1935 Distinguished Chair of Energy.

The study by Wadia, Kammen and Alivisatos, available online at http://pubs.acs.org, will appear in the March print issue of Environmental Science & Technology. Wadia will discuss the report on April 14 at the upcoming spring meeting of the Materials Research Society, to be held at the Moscone Center in San Francisco.

The work was supported by the U.S. Environmental Protection Agency, the Energy Foundation, the Karsten Family Foundation Endowment of the Renewable and Appropriate Energy Laboratory and the Class of 1935.

Cheaper materials could be key to low-cost solar cells

Wednesday, August 27, 2008

Hydrogen Extraction From Unrefined Crude Oil Is Near To Reality.

ARGONNE, Ill. (Aug. 22, 2008), A commercial-scale process to extract and reuse pure hydrogen from the hydrogen sulfide that naturally contaminates unrefined oil, including oil sands, is one step closer to reality thanks to a collaboration between the U.S. Department of Energy's Argonne National Laboratory and Kingston Process Metallurgy Inc. (KPM) of Kingston, Ontario.

Argonne and KPM researchers have invented a molten copper reactor, an innovative process technology that is more energy-efficient than existing methods, according to Gregory Krumdick, an engineer in Argonne's Energy Systems Division. Moreover, the pure hydrogen gas stream that it extracts can be used to upgrade and clean crude oil and petroleum products and aid in a number of refining processes, KPM President Boyd Davis said. Krumdick, Davis, Alain Roy, KPM's vice president of operations, and former Argonne researcher John Hryn invented the technology.

In the reactor, hydrogen sulfide gas is first separated from the crude oil stock, using technology already in place. This gas is then bubbled though molten copper, which releases pure hydrogen. The hydrogen is then captured for use as a valued product. As the sulfur reacts with the copper, the copper is gradually turned into copper sulfide.

Argonne is collaborating with KPM, a bench-scale process development firm, under a work-for-others agreement. KPM is supported in part by Natural Resources Canada (NRCan), which has provided $600,000 (Canadian) for the research over the last three years.

In addition to generating pure hydrogen, the process creates another valuable product, concentrated sulfuric acid, which is used widely in the chemical industry and which has become a valued agricultural commodity. The concentrated sulfuric acid is created when copper sulfide is reacted with air to recover the pure copper, releasing a concentrated stream of sulfur dioxide which is then reacted with water. The copper is then reused in the process with negligible losses, Krumdick said.

The reactions between the hydrogen sulfide and copper and the copper sulfide and air release energy that helps to heat the system, enabling the researchers to harvest the products efficiently, Krumdick said. The system operates at a temperature of about 1,200 degrees Celsius.

"Technologies that are in use today, including the widely used Claus process, are more energy- and capital-intensive," Krumdick said. "In addition, they also lose the hydrogen in the process. Instead of capturing the hydrogen from the hydrogen sulfide, the Claus process ends up converting it into water."

The multi-step Claus process was invented more than 100 years ago and is the most widely used method for removing the hydrogen sulfide that is present in crude oil and raw natural gas. The Claus process is also believed to be more limited than the Argonne-KPM process in terms of the other types of impurities it can handle. Costly energy-intensive modules that scrub other contaminants, such as ammonia, methane and carbon dioxide from raw oil and natural gas must be separately attached to Claus processing facilities.

Argonne computer modeling strongly indicated that the Argonne-KPM process would deal with those other impurities, a conclusion that was later experimentally proven. Contaminants such as ammonia and various hydrocarbons are reformed to their elemental constituents, providing an added benefit to the process, Krumdick said.

Argonne and KPM continue to scale up their experimental work to further test the process. "Our goal is to develop a pilot scale reactor," Krumdick said. "If a pilot plant demonstrates that the process is a major improvement over existing technology and we believe it is it will spur the interest of industries that use a process to separate hydrogen sulfide," Davis added.

"Companies will be able to retrofit their facilities with the process technology or construct new plants that incorporate it," Davis added. "In the meantime, we are working with Argonne to use the technology for other energy applications, such as gas cleanup for Integrated Gassification Combined Cycle plants."

Argonne and KPM began working on the technology in 2003 as a laboratory-directed research and development proof-of-concept project.

Kingston Process Metallurgy is an industrial process research and development company. It focuses on providing quantitative data to support the development of novel processes and explores business opportunities in collaboration with customers and partners. It has clients from around the world who use KPM's expertise in process development and laboratory experimentation.

Natural Resources Canada (NRCan) works to ensure the responsible development of Canada's natural resources, including energy, forests, minerals and metals. It has expertise in earth sciences that it uses to build and maintain an up-to-date knowledge base of Canada's landmass and resources. NRCan develops policies and programs that enhance the contribution of the natural resources sector to the economy and improve the quality of life of residents, and represents Canada at the international level to meet the country's global commitments related to natural resources.

Argonne National Laboratory brings the world's brightest scientists and engineers together to find exciting and creative new solutions to pressing national problems in science and technology. The nation's first national laboratory, Argonne conducts leading-edge basic and applied scientific research in virtually every scientific discipline. Argonne researchers work closely with researchers from hundreds of companies, universities, and federal, state and municipal agencies to help them solve their specific problems, advance America 's scientific leadership and prepare the nation for a better future. With employees from more than 60 nations, Argonne is managed by UChicago Argonne, LLC for the U.S. Department of Energy's Office of Science.

For more information, please contact Angela Hardin (630/252-5501 or ahardin@anl.gov) at Argonne.

Tuesday, July 08, 2008

DOE to Guarantee Billions in Loans for Efficiency, Renewables

The U.S. Department of Energy (DOE) today announced three solicitations for a total of up to $30.5 billion in federal loan guarantees for projects that employ advanced energy technologies and that avoid, reduce or sequester anthropogenic emissions of air pollutants or greenhouse gases.

NEWS MEDIA CONTACT: Angela Hill, (202) 586-4940
FOR IMMEDIATE RELEASE Monday, June 30, 2008
DOE Announces Solicitations for $30.5 Billion in Loan Guarantees
Second Round of Solicitations includes renewable energy, nuclear, and ‘front-end’ nuclear power facility projects
WASHINGTON, DC –The U.S. Department of Energy (DOE) today announced three solicitations for a total of up to $30.5 billion in federal loan guarantees for projects that employ advanced energy technologies that avoid, reduce or sequester air pollutants or greenhouse gas emissions. The three solicitations are in the areas of energy efficiency, renewable energy and advanced transmission and distribution technologies; nuclear power facilities; and advanced nuclear facilities for the ‘front-end’ of the nuclear fuel cycle. This marks the second round of solicitations for DOE’s Loan Guarantee Program, which encourages the commercial use of new or significantly improved energy technologies, and is an important step in paving the way for clean energy projects.
In a Fiscal Year (FY) 2008 loan guarantee implementation plan sent to Congress in April, DOE outlined plans to issue its second round of solicitations concurrently no later than June 2008 for energy efficiency, renewable energy and advanced transmission and distribution projects (up to $10 billion); nuclear power facilities (up to $18.5 billion); and advanced nuclear facilities for the “front-end” of the nuclear fuel cycle (up to $2 billion).
Later this summer, DOE intends to issue a solicitation for loan guarantee applications for advanced fossil energy projects (up to $8 billion). The authority to issue loan guarantees in the amounts specified in these solicitations was provided to DOE in the Consolidated Appropriations Act, 2008 and is consistent with the Department’s FY 2009 Congressional Budget Request. “Loan guarantees from the Department will enable project developers to bridge the financing gap between pilot and demonstration projects to full commercially viable projects that employ new or significantly improved energy technologies,” Jeffrey F. Kupfer, the Acting Deputy Secretary of Energy, said. “Projects supported by loan guarantees will help meet President Bush’s goal of diversifying our nation's energy mix with energy projects that will improve the environment while increasing energy efficiency.”
The Department issued a Request for Information on April 11, 2008 and held subsequent public meetings in Washington, D.C. and Palo Alto, California to receive input on the development of the solicitation for projects in the energy efficiency, renewable energy and advanced transmission and distribution areas.
The loan guarantee process is organized into four phases: application, project evaluation, conditional commitment, and final approval and closing of a Loan Guarantee Agreement. Selection criteria for the clean energy projects under these solicitations will focus on a project’s ability to avoid, reduce or sequester air pollutants or greenhouse gas emissions; the speed with which the technologies can be commercialized; the prospect of repayment of the guaranteed debt; and the potential for long-lasting success of these technologies in the marketplace.
Today’s round of solicitations builds off of the previous solicitation issued by DOE which supported energy efficiency, renewable energy and fossil energy projects. DOE is currently reviewing the applications received to date as a result of the first solicitation.
Loan guarantees issued by DOE will be backed by the full faith and credit of the United States, and will facilitate the early commercial use of new or significantly improved technologies that will help fulfill President Bush’s goals of reducing our reliance on imported sources of energy by increasing energy efficiency, diversifying our nation’s energy mix, and improving the environment. For additional information on this solicitation and the Department’s Loan Guarantee Program, visit www.lgprogram.energy.gov.